Research Journal of Applied Sciences

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Equilibrium Studies of the Reactions of Tricarbonyl (2-methoxycyclohexadienyl) Iron (II) Cation with Some Amine Nucleophiles

Timothy. I. Odiaka and Adebomi. A. Adetoye
Page: 958-962 | Received 21 Sep 2022, Published online: 21 Sep 2022

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Abstract

The equilibrium study of the reactions of [(1-5- -2 MeOC₆H₆) Fe (CO)₃]BF₄ with 4-dimethylaminopyridine, 2-aminopyrimidine and P-toluidine was studied in nitromethane at room temperature spectrophotometrically. The results show that the rate of reaction is dependent on the basicity of nucleophiles with the rate of reaction decreasing in the order 4-dimethylaminopyridine > 2-aminopyrimidine > P-toluidine. Our findings also indicate that the forward reactions are being favored than the reverse dissociation reactions since K_eqm>1 in each case.

How to cite this article:

Timothy. I. Odiaka and Adebomi. A. Adetoye . Equilibrium Studies of the Reactions of Tricarbonyl (2-methoxycyclohexadienyl) Iron (II) Cation with Some Amine Nucleophiles.
DOI: https://doi.org/10.36478/rjasci.2007.958.962
URL: https://www.makhillpublications.co/view-article/1815-932x/rjasci.2007.958.962