TY  - JOUR
T1  - Thermal, Electrical and Structural Characterization of MI-AgI (M = Na, Li) Systems above Room Temperatures
AU - Trujillo, J.A. AU - Garcia-Muriel, A. AU - Ortiz-Ortiz, Ruben-Dario AU - Quinones, E.E. AU - Marin-Ramirez, Ana-Magnolia 
JO  - Journal of Engineering and Applied Sciences
VL  - 11
IS  - 12
SP  - 2709
EP  - 2712
PY  - 2016
DA  - 2001/08/19
SN  - 1816-949x
DO  - jeasci.2016.2709.2712
UR  - https://makhillpublications.co/view-article.php?doi=jeasci.2016.2709.2712
KW  - X-ray diffraction
KW  -Phase transition
KW  -ionic conductivity
KW  -system
KW  -energy
AB  - The thermal (DSC) and electrical (IS) and structural (XRD) behavior of MI-AgI (M = Na, Li) systems
were investigated for temperatures above 300 K. The slow evaporation method was used to synthesized
samples under concentrations given by the relationship: xAgI-(1-x) NaI and xAgI-(1-x) LiI with x = 0.8. The
characterization results reveal how the AgI conductivity jump at T = 420 K, this was reduced when the Li+or
Na+was interchanged for Ag+ion due to the cooperative effects of ion-ion and ion-lattice interactions. The
transition temperature of the system decreased as the doping concentration was increased. The reached
conductivities (>10-4 S/cm) and the low activated energy values (lower than those found with AgI) show the
importance of xAgI-(1-x)LiI systems, allowing a wider knowledge of the behavior of solid conductors developed
based on silver iodide compounds.
ER  -