Osei Akot, Ernest Abankwa,
Heavy Metals Contamination and Speciation in Sediments of the Owabi Reservoir,
Environmental Research Journal,
Volume 8,Issue 1,
2014,
Pages 10-16,
ISSN 1994-5396,
erj.2014.10.16,
(https://makhillpublications.co/view-article.php?doi=erj.2014.10.16)
Abstract: Heavy metals are potentially toxic to humans and the environment. Metal toxicity
depends on the chemical forms in which they exist. In this research, an investigation
was conducted to study the contamination and speciation of some heavy metals
(Cu, Zn, Pb and Cu) in sediments from the Owabi reservoir in Kumasi, Ghana.
The mean concentrations of Pb and Zn were higher than the Continental Average
Shale (CAS) and were beyond the Threshold Effect Level (TEL), implying contamination
of these metals in the sediments. This observation was also confirmed by geoaccumulation
index calculations. Canonical correlation analysis revealed that leaching of
Zn is associated with pH while co-precipitation of Fe and Pb is also associated
with EC. Speciation analysis showed significant amount of Zn Cu and Pb were
available in the Fe-Mn fractions. But major amount of Fe was found in the residual
fraction. The amount of Zn and Pb present in the bioavailable from have the
potential to induce ecological risk. The results stresses that discharge of
untreated waste into streams serving the reservoir should be avoided to reduce
contamination since the contaminants found in this research are mainly release
into the environment through human activities. Factor analysis showed that site
S1 and S3 are the most polluted sites.
Keywords: Owabi;heavy metals;metal speciation;factor analysis;Ecological risk;sediments